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xp075287

Time-resolved fluorescence spectroscopy with micro-environment on Eu (TTA) 3 and Eu (...

Can Horroeks. W. D. andSudnick, R. A ~ '~' out1. ('EnJ.R. .198 L; 14 (L2): 384RiehardSOI1.F.S.Ch state. RnJ.1982; 82:54 lWright, 』. C., ModernFluorescenceSl: ~' vtroscopy (Ed.Wehry, E.I. ), Vo1.4 · PlenumPNewYorkandLondon.1981-51Sabb ~ im.N. has 1} d.. PhotoehemistryandP1 【0physlcsofCoordinationcompounds (Ed.Yersin, HandVoglex, A.), springer-Verlag.Berlin, l987: 25Bergaya-F.andVanLMmme. H., J.CS.b a86 Howie magnitude. Luminescence .1988; 9 (a) :223-85 A nnn;]] il5; l; [[[9] [1O] [11] [12] [13] [H] deCosta, S. M.B. Rights aL.J.Photachem .. 1980'12: 31, rund0, P.andFendbr, J.H. + d.Am.Chem.S.,[link widoczny dla zalogowanych], 198 {~; 102:176 ORuaudel-ixier + A. eta1., ThinSolidFilms, 1988; 160:107 Twarowski.A.J.etal, Chem.Phys.Lelters.1976; 41:329, etc. AND WESTERN UNIVERSITIES .1989; 10:434 Turin + N.J. + ModernMolecularPhotochemistry. hhEd.rTheBenjamin / CummlngsPublishingCompany.Inc., Cafifornia, 1978:305 TheStudyofEu (TTA) 3andEu (DB) 3LuminescenceinMicroenvironmentsbyTime-resolvedF! uorescenceSpectrum turn to the circle. FeiHaosheng, TianKeandLiTiejlntdilinU1mr ☆ f, Changchun) AbstractTheluminescenceofEucomplexesinfluencedbymicroenvironmentsandthefluo-reseeneequenchingofEu (TTA) andEu (DB) 3withNCS- addedhavebeenstudiedwithtime-resolvedfluorescencespectrometry. Theexperimentsshowthattherelaxationratek0oftheDolevelinEuincreaseswiththeintroduceofNCS-anions. Intheresult, themlcroenvironmentchangecausedbytheintroduceofNCS-anionsinfluencesonLaporteselectivelaw0fEu KeywordsEucomplex. mlcroenvironment. quenchingofexcitedstate, time-resoivedfluo-re ~ a2eneespectrum86